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- W2037112903 abstract "A benzo[a]anthraquinone ring system, common to a group of angucycline antibiotics, has been prepared by a unique cascade of reactions. The reaction sequence was initiated by a Suzuki-Miyaura cross-coupling between a bromoquinone and vinyl boronic anhdyride. The reaction product is proposed to undergo a 6π-electron cyclization triggered by reductive activation of the quinone. The reaction process is proposed to be autocatalytic." @default.
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- W2037112903 date "2012-03-01" @default.
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- W2037112903 title "Cascade assembly of the benz[a]anthraquinone ring system common to the angucycline antibiotics" @default.
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- W2037112903 doi "https://doi.org/10.1016/j.tetlet.2011.12.126" @default.
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