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- W2037128372 abstract "Twelve force constants in the general quartic force field of carbon dioxidehave been determined by the least squares method from spectroscopic data on C12O216 and C13O216 together with the four third-order parameters, i.e., λ1, λ2, λ3, and σ which appear in the Fermi coupling off-diagonal elements. It is shown that inclusion of these third-order parameters is indispensable to obtain a reasonable set of anharmonic force constants. From these force constants, consistent sets of vibrational constants (ωs, χss′), Fermi coupling constants (We), and rotation-vibration coupling constants (αs) have been derived for C12O216, C13O216, C12O16O18 and C13O16O18. The calculated vibrational energy levels and rotational constants agree well with those obtained experimentally. A potential energy contour map of carbon dioxide is also given and discussed." @default.
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- W2037128372 date "1968-04-01" @default.
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- W2037128372 title "General anharmonic force constants of carbon dioxide" @default.
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- W2037128372 doi "https://doi.org/10.1016/s0022-2852(68)80018-9" @default.
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