Matches in SemOpenAlex for { <https://semopenalex.org/work/W2037131458> ?p ?o ?g. }
Showing items 1 to 78 of
78
with 100 items per page.
- W2037131458 endingPage "1357" @default.
- W2037131458 startingPage "1351" @default.
- W2037131458 abstract "Reaction of Ti(OiPr)4 with chloroacetic acids (1:1 and 1:2 stoichiometric ratio) in toluene gives the corresponding mono-and bis-substituted products in quantitative yield. The products Ti(OiPr)3(OOCR) (R = CH2Cl 1a, CHCl2 1b, CCl3 1c) are proposed to have a dimeric structure on the basis of 1H,13C NMR and IR spectroscopy. On standing in toluene, solutions of 1c form the trinuclear species Ti3(μ3-O)(μ3-OiPr)2(OiPr)5(μ-O2CCCl3)3 (2) with the three titanium atoms forming an isosceles triangle and the μ3-O moiety at the center. On standing in toluene, solutions of 1b form a hexanuclear product Ti6(μ3-O)6(OiPr)6(μ-O2CCHCl2)6 (3), the structure of which consists of two stacked six-membered [Ti-μ3-O]3 rings connected by Ti–O bonds. Under comparable conditions, the bis-substituted product Ti(OiPr)2(O2CCCl3)2 (4c) forms the dinuclear species Ti2(μ-O)(OiPr)2(HOiPr)2(μ-O2CCCl3)2(O2C–CCl3)2 (5) in which the two symmetric octahedral titanium centers are bonded to a common oxygen atom." @default.
- W2037131458 created "2016-06-24" @default.
- W2037131458 creator A5019588157 @default.
- W2037131458 creator A5021662681 @default.
- W2037131458 creator A5085011812 @default.
- W2037131458 date "2000-06-01" @default.
- W2037131458 modified "2023-09-23" @default.
- W2037131458 title "Synthesis and Solid-State Characterization of Isopropoxy CarboxylateClusters of TiIV" @default.
- W2037131458 doi "https://doi.org/10.1002/(sici)1099-0682(200006)2000:6<1351::aid-ejic1351>3.0.co;2-o" @default.
- W2037131458 hasPublicationYear "2000" @default.
- W2037131458 type Work @default.
- W2037131458 sameAs 2037131458 @default.
- W2037131458 citedByCount "0" @default.
- W2037131458 crossrefType "journal-article" @default.
- W2037131458 hasAuthorship W2037131458A5019588157 @default.
- W2037131458 hasAuthorship W2037131458A5021662681 @default.
- W2037131458 hasAuthorship W2037131458A5085011812 @default.
- W2037131458 hasConcept C115624301 @default.
- W2037131458 hasConcept C134121241 @default.
- W2037131458 hasConcept C144082473 @default.
- W2037131458 hasConcept C155647269 @default.
- W2037131458 hasConcept C178790620 @default.
- W2037131458 hasConcept C185592680 @default.
- W2037131458 hasConcept C191897082 @default.
- W2037131458 hasConcept C192562407 @default.
- W2037131458 hasConcept C198819137 @default.
- W2037131458 hasConcept C2776568683 @default.
- W2037131458 hasConcept C2778142098 @default.
- W2037131458 hasConcept C506065880 @default.
- W2037131458 hasConcept C66974803 @default.
- W2037131458 hasConcept C71240020 @default.
- W2037131458 hasConcept C8010536 @default.
- W2037131458 hasConceptScore W2037131458C115624301 @default.
- W2037131458 hasConceptScore W2037131458C134121241 @default.
- W2037131458 hasConceptScore W2037131458C144082473 @default.
- W2037131458 hasConceptScore W2037131458C155647269 @default.
- W2037131458 hasConceptScore W2037131458C178790620 @default.
- W2037131458 hasConceptScore W2037131458C185592680 @default.
- W2037131458 hasConceptScore W2037131458C191897082 @default.
- W2037131458 hasConceptScore W2037131458C192562407 @default.
- W2037131458 hasConceptScore W2037131458C198819137 @default.
- W2037131458 hasConceptScore W2037131458C2776568683 @default.
- W2037131458 hasConceptScore W2037131458C2778142098 @default.
- W2037131458 hasConceptScore W2037131458C506065880 @default.
- W2037131458 hasConceptScore W2037131458C66974803 @default.
- W2037131458 hasConceptScore W2037131458C71240020 @default.
- W2037131458 hasConceptScore W2037131458C8010536 @default.
- W2037131458 hasIssue "6" @default.
- W2037131458 hasLocation W20371314581 @default.
- W2037131458 hasOpenAccess W2037131458 @default.
- W2037131458 hasPrimaryLocation W20371314581 @default.
- W2037131458 hasRelatedWork W1503496274 @default.
- W2037131458 hasRelatedWork W1974828456 @default.
- W2037131458 hasRelatedWork W1990012766 @default.
- W2037131458 hasRelatedWork W2004915080 @default.
- W2037131458 hasRelatedWork W2009660202 @default.
- W2037131458 hasRelatedWork W2015454740 @default.
- W2037131458 hasRelatedWork W2022137321 @default.
- W2037131458 hasRelatedWork W2025489355 @default.
- W2037131458 hasRelatedWork W2046632354 @default.
- W2037131458 hasRelatedWork W2059343744 @default.
- W2037131458 hasRelatedWork W2060719446 @default.
- W2037131458 hasRelatedWork W2080519211 @default.
- W2037131458 hasRelatedWork W2088348279 @default.
- W2037131458 hasRelatedWork W2089008515 @default.
- W2037131458 hasRelatedWork W2152271568 @default.
- W2037131458 hasRelatedWork W2321988075 @default.
- W2037131458 hasRelatedWork W2441854903 @default.
- W2037131458 hasRelatedWork W2766551803 @default.
- W2037131458 hasRelatedWork W2767669090 @default.
- W2037131458 hasRelatedWork W2981378363 @default.
- W2037131458 hasVolume "2000" @default.
- W2037131458 isParatext "false" @default.
- W2037131458 isRetracted "false" @default.
- W2037131458 magId "2037131458" @default.
- W2037131458 workType "article" @default.