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- W2037166704 abstract "The correct (event weighted) average of kt, 〈kt〉, has been calculated for pseudostationary laser-induced polymerization for a kinetic scheme with chain-length dependent termination and compared to the average k̄t obtained by formally solving for kt the expression for the second moment of the chain-length distribution valid for chain-length independent termination (represented by the product of rate of polymerization νp and weight average degree of polymerization P̄w). It is shown that there is a fair agreement between the two quantities. This may be used to recover experimentally the power-law governing the dependence of kt on chain-length, especially its exponent." @default.
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- W2037166704 date "1997-12-01" @default.
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- W2037166704 title "Chain-length dependent termination in pulsed-laser polymerization, 2. On the prospects of determining the bimolecular termination constant kt from the second moment of the chain-length distribution" @default.
- W2037166704 doi "https://doi.org/10.1002/marc.1997.030181202" @default.
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