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- W2037169391 abstract "This paper presents the melting relations for the entire system sulfursilver, together with a study of the transition behavior of silver sulfide. Silver sulfide melts at 838±2°C and undergoes two transitions in the solid state, each of which occurs at variable temperatures over a limited range of composition. The mean temperatures for the lower transition (Ag2S III=Ag2S II) are 177.8°C in sulfur-rich and 176.3°C for silver-rich preparations; for the upper transition (Ag2S II=Ag2S I) they are, respectively, 622°C and 586°C. A discussion is given of a possible mechanism for the incorporation of a limited excess of sulfur or silver into the lattice, as bised on the semi-conducting properties of the substance and lattice disorderThe melts of silver sulfide form two liquid layers with sulfur-rich melts at 740°C, and with silver-rich melts at 906°C. The eutectic with sulfur is at 119.3°C, and with silver, at 804°C." @default.
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- W2037169391 date "1946-01-01" @default.
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- W2037169391 title "Phase relations in the system sulfur—Silver and the transitions in silver sulfide" @default.
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- W2037169391 doi "https://doi.org/10.1029/tr027i003p00364" @default.
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