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- W2037169944 abstract "Abstract The polarized infra-red absorption spectra of single crystals of trans-[CoX2(en)2]Y (X = Cl−, Br−, Y = ClO4−, NO3−, I−) have been observed from 5000 to 400 cm−1. The spectra show no distinct dichroism in the NaCl region where most of absorption bands are due to the vibrations of CH2 and NH2 groups of ligand ethylenediamine. However, the spectra in the KBr region exhibit three polarized absorption bands at about 590, 510 and 470 cm−1, which are characteristic to the chelate ring. The dichroism of these bands has been discussed in relation to the crystal structure of these compounds. The band at 510 cm−1 is mainly due to the CoN stretching vibration, whereas the other two bands, 590 and 470 cm−1, are assigned to the skeletal ring deformation coupled with the CoN stretching vibration." @default.
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- W2037169944 date "1966-04-01" @default.
- W2037169944 modified "2023-09-27" @default.
- W2037169944 title "Infra-red dichroism of trans-dihalogenobis(ethylenediamine)-cobalt (III) complexes" @default.
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- W2037169944 doi "https://doi.org/10.1016/0371-1951(66)80089-9" @default.
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