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- W2037206700 abstract "Isothermal resistance measurements and hot-stage optical microscopy were used to simultaneously follow the loss of oxygen and the disappearance of the twin structure in single-crystal ${mathrm{YBa}}_{2}$${mathrm{Cu}}_{3}$${mathrm{O}}_{7mathrm{ensuremath{-}}mathrm{ensuremath{delta}}}$ from 590--720ifmmode^circelsetextdegreefi{}C. Oxygen out-diffusion was found to follow surface-reaction-limited conditions with an activation energy of 1.2ifmmodepmelsetextpmfi{}0.1 eV. Although the crystal was driven through the orthorhombic-tetragonal phase transformation during the isothermal anneals, no anomalous resistance behavior was observed. This suggests that previous observations of anomalous resistance behavior in bulk ceramics may not be intrinsic to ${mathrm{YBa}}_{2}$${mathrm{Cu}}_{3}$${mathrm{O}}_{7mathrm{ensuremath{-}}mathrm{ensuremath{delta}}}$. The difference between oxygen in-diffusion and out-diffusion kinetics is discussed in relation to the twin structure observed near the orthorhombic-tetragonal phase transformation." @default.
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- W2037206700 date "1991-01-01" @default.
- W2037206700 modified "2023-09-27" @default.
- W2037206700 title "Resistance measurements and oxygen out-diffusion near the orthorhombic-tetragonal phase transformation in single-crystalYBa2Cu3O7−δ" @default.
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- W2037206700 doi "https://doi.org/10.1103/physrevb.43.441" @default.
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