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- W2037207960 abstract "1,3-Indandione (1) readily condenses with benzene and undergoes selective ionic hydrogenation with cyclohexane when activated by superacids, such as CF3SO3H, AlCl3 and AlBr3 to give 3,3-diphenyl-1-indanone (4) and 1-indanone (7), respectively. Combination of these reactions in ‘one-pot’ yields 3-phenyl-1-indanone (5). In addition, similar reactions have been carried out using the regenerable solid acid, HUSY-zeolite, providing an effective excess of acidic sites. The mechanism of these reactions, with potential involvement of superelectrophilic dicationic intermediates, is discussed." @default.
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- W2037207960 date "2007-08-01" @default.
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- W2037207960 title "Superacidic and HUSY-zeolite activation of 1,3-indandione: reactions with benzene and cyclohexane" @default.
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- W2037207960 doi "https://doi.org/10.1016/j.tetlet.2007.06.023" @default.
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