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• W2037211052 endingPage "4558" @default.
• W2037211052 startingPage "4553" @default.
• W2037211052 abstract "Cyano-substituted bi- and terthiophene derivatives have been synthesized and characterized both electrochemically and optically. The experimental data are compared to the results of quantum-chemical calculations in order to rationalize the evolution of the frontier levels of the thiophene oligomers as a function of the number and position of the cyano substituents. This issue is of particular relevance in the context of organic light-emitting diodes and field-effect transistors to determine the substitution pattern required for the design of efficient electron-transporting (n-type) oligothiophene derivatives. The experimental and theoretical results demonstrate that the cyano functionalization allows for a fine-tuning of the electronic and optical properties of the thiophene compounds." @default.
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• W2037211052 date "1997-06-01" @default.
• W2037211052 modified "2023-09-25" @default.
• W2037211052 title "Tuning of the Electronic and Optical Properties of Oligothiophenes via Cyano Substitution: A Joint Experimental and Theoretical Study" @default.
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• W2037211052 doi "https://doi.org/10.1021/jp970085z" @default.
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