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- W2037221507 abstract "The synthesis of six linear trimetallic compounds of the type [η5-RC5H4 (CO)3E]2Hg (E = Cr, Mo, W ; R = Me, Et, n-Bu), from phenylmercuric chloride and corresponding transition metal lithium salts [η5-RC5H4(CO)3E]Li is described. The new compounds were characterized by elemental analysis, MS, IR and 1H NMR spectroscopy and the structure of [η5-EtC5H4(CO)3Cr]2Hg as determined by X-ray diffraction. The CrHgCr skeleton of the molecule is diagonal with some departure from linearity and the coordination geometry around each chromium atom approximates to a square-based pyramid with one substituted cyclopentadienyl ring occupying the apical position." @default.
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- W2037221507 date "1994-07-01" @default.
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- W2037221507 title "Synthesis and characterization of trimetallic complexes [η5-RC5H4(CO)3E]2Hg (E = Cr, Mo, W ; R = Me, Et, n-Bu). Crystal structure of [η5-EtC5H4(CO)3Cr]2Hg" @default.
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