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- W2037223652 abstract "A new chemodosimeter for detection of Hg(II) ions based on boron-dipyrromethene (BODIPY) is developed. The 3-(pyridine-4-thione)BODIPY was synthesized in high yield by treating 3-(pyridine-4-one)BODIPY with Lawesson's reagent. The 3-(pyridine-4-thione) BODIPY was confirmed by HR-MS mass, 1H, 1H–1H COSY, 19F and 11B NMR techniques. In 1H NMR, the protons which are adjacent to sulfur in 3-(pyridine-4-thione)BODIPY showed ∼1 ppm downfield shift compared to equivalent protons in 3-(pyridine-4-one)BODIPY. The absorption and electrochemical properties experienced slight changes in 3-(pyridine-4-thione)BODIPY compared to 3-(pyridine-4-one)BODIPY. The compound 3-(pyridine-4-thione)BODIPY is very weakly fluorescent compared to 3-(pyridine-4-one)BODIPY. Furthermore, 3-(pyridine-4-thione)BODIPY can be used as an exclusive chemodosimeter for Hg2+ ion as it shows significant enhancement in the fluorescence intensity and a dramatic visible color change from pink to fluorescent green in the presence of Hg(II) ions." @default.
- W2037223652 created "2016-06-24" @default.
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- W2037223652 date "2012-10-01" @default.
- W2037223652 modified "2023-10-17" @default.
- W2037223652 title "3-(Pyridine-4-thione)BODIPY as a chemodosimeter for detection of Hg(II) ions" @default.
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- W2037223652 doi "https://doi.org/10.1016/j.dyepig.2012.03.015" @default.
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