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- W2037238230 endingPage "2384" @default.
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- W2037238230 abstract "The reaction of 2-(diphenylphosphino)-N-[2-(diphenylphosphino)benzylidene]benzeneamine (PNCHP) with 0.5 equivalents of [{RhCl(1,5-cyclooctadiene)}2] affords the extremely, air-sensitive compound, [RhCl(PNCHP-κ3P,N,P)]. This reacts with carbon monoxide to afford [RhCl(CO)(PNCHP-κ3P,N,P)] which rearranges in dichloromethane solution to [Rh(CO)(PNCHP-κ3P,N,P)]Cl · HCl. The single crystal structure of [Rh(CO)(PNCHP-κ3P,N,P)]Cl · HCl shows the Rh to be in a square planar environment with the HCl molecule held via hydrogen bonding in the lattice. NMR experiments show the coordinated chloride in [RhCl(PNCHP-κ3P,N,P)] can be substituted with tetrahydrofuran, acetonitrile or triphenylphosphine and the complex undergoes oxidative addition with dichloromethane to yield [Rh(CH2Cl)Cl2(PNCHP-κ3P,N,P)]." @default.
- W2037238230 created "2016-06-24" @default.
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- W2037238230 date "2004-06-01" @default.
- W2037238230 modified "2023-09-25" @default.
- W2037238230 title "A rhodium(I) complex containing a mixed donor `P2N' tridentate ligand" @default.
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- W2037238230 doi "https://doi.org/10.1016/s0020-1693(03)00483-3" @default.
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