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- W2037250697 abstract "The Q branch of the ν3 stretching fundamental of 32SF6 (ca. 947.6–948.3 cm−1) has been recorded at 109–142 K with a resolution of <10−4 cm−1, and the individual transitions have been assigned. Several series of lines arising from different subbranches can be followed up to high J values (J ≈ 80 in one case). Some of these subbranches form prominent band-heads that dominate the gross structure of the Q branch, especially at higher temperatures. A moderately strong transition at 947.742 cm−1, displaced −8 MHz from the P(16) CO2 laser line, has been assigned as Q(38) F10 + E0 + F20; 39 other transitions that fall within ±300 MHz of the laser line have also been identified. The Q branch of 33SF6, present in natural abundance (0.76%), has been recored and analyzed; the isotope shift is 8.97 cm−1." @default.
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- W2037250697 date "1977-11-01" @default.
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- W2037250697 title "The ν3 Q branch of SF6 at high resolution: Assignment of the levels pumped by P(16) of the CO2 laser" @default.
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