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• W2037266746 startingPage "1554" @default.
• W2037266746 abstract "The secondary structure of an optically active polythiourethane [(CH2C*H(CO2Me)NHCOS)n] was evaluated with 1H NMR, IR, and circular dichroism (CD) spectroscopy. Hydrogen bonds between the carbonyl and NH groups in the thiourethane group constrained the main chain of the chiral polythiourethane precisely under the direction of chirality in the main chain, whereas the racemic polymer was also constrained but randomly. The secondary structure of the polythiourethane in CHCl3 changed noticeably in the presence or absence of trifluoroacetic acid, which eliminated constraining intramolecular hydrogen bonds. IR spectroscopy suggested that the secondary structure was almost identical in solid and solution states. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 1554–1561, 2005" @default.
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• W2037266746 date "2005-01-01" @default.
• W2037266746 modified "2023-09-25" @default.
• W2037266746 title "Observation of optical activity in polythiourethane obtained by the controlled cationic ring-opening polymerization of chiral cyclic thiourethane derived from serine" @default.
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• W2037266746 doi "https://doi.org/10.1002/pola.20624" @default.
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