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- W2037272493 abstract "The complexation processes between Cu(II) and the antihypotension drug Effortil (HEff) at different reaction conditions lead to the formation of two types of complex — a mononuclear violet one, CuEff2·2CH3OH, and the binuclear green Cu2Eff2Cl2. Monocrystals of the mononuclear CuEff2·2CH3OH complex were isolated and their structure determined by X-ray diffraction. Copper is coordinated through O− and N of OH and NH groups from the ligands in a perfectly flat tetragon. The crystal structure also includes two solvent CH3OH molecules per CuEff2 unit. The CuEff2 fragments are linked by hydrogen bonds. The binuclear Cu2Eff2Cl2 complex was characterized using electronic and IR spectra, EPR, magnetochemical, calorimetric, thermogravimetric methods and elemental analysis. The complex contains bidentately bound monoanionic ligands and chloride ions. Each Cu atom is coordinated with NH, and bridged by the deprotonated OH group of Effortil with the second Cu center. The chloride ions are coordinated with copper as terminal ligands." @default.
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- W2037272493 date "2000-07-01" @default.
- W2037272493 modified "2023-09-24" @default.
- W2037272493 title "Complexes of Cu(II) with α-[(ethylamino)methyl]-3-hydroxy, benzenemethanol (Effortil). Crystal structure of the mononuclear Cu(II) complex with Effortil" @default.
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- W2037272493 doi "https://doi.org/10.1016/s0277-5387(00)00468-x" @default.
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