Matches in SemOpenAlex for { <https://semopenalex.org/work/W2037282693> ?p ?o ?g. }
- W2037282693 endingPage "1885" @default.
- W2037282693 startingPage "1873" @default.
- W2037282693 abstract "In addition to the earlier[1] demonstrated C–O bond elongation between the anionic carbon atom and oxygen in α-lithiated ethers which indicates a carbenoid character of these compounds we provide further evidence for this property in this publication. Thus, α-lithiated ethers RCH(Li)–OR' react as electrophiles with nucleophiles R' Li to give RCH(Li)–R' + LiOR', and the 13C-NMR signal of the carbenoid C atom is shifted downfield (compared to the 13C signal of the corresponding non-lithiated compound). Since the latter two observations are also made in the Li/Hal carbenoid series, α-lithiated ethers indeed are Li/oxygen carbenoids. Furthermore, for the first time we have calculated the 13C shifts of carbenoid C atoms in the Li/oxygen carbenoid series by means of the IGLO method: the calculated data agree nicely with the experimental ones. They even allow the preferred bridged structure in solution to be determined." @default.
- W2037282693 created "2016-06-24" @default.
- W2037282693 creator A5011318124 @default.
- W2037282693 creator A5030717252 @default.
- W2037282693 creator A5052727959 @default.
- W2037282693 creator A5061708854 @default.
- W2037282693 creator A5085494905 @default.
- W2037282693 date "1993-08-01" @default.
- W2037282693 modified "2023-10-16" @default.
- W2037282693 title "α‐Oxygen‐Substituted Organolithium Compounds and their Carbenoid Nature: Reactions with RLi and Other Nucleophiles, Experimental and IGLO‐Calculated <sup>13</sup> C‐NMR Shifts of the Carbenoid C Atom" @default.
- W2037282693 cites W153024872 @default.
- W2037282693 cites W1589396791 @default.
- W2037282693 cites W160281234 @default.
- W2037282693 cites W1892390732 @default.
- W2037282693 cites W1965629878 @default.
- W2037282693 cites W1966554361 @default.
- W2037282693 cites W1975300963 @default.
- W2037282693 cites W1976185634 @default.
- W2037282693 cites W1976238064 @default.
- W2037282693 cites W1978929922 @default.
- W2037282693 cites W1979157519 @default.
- W2037282693 cites W1982631262 @default.
- W2037282693 cites W1984682974 @default.
- W2037282693 cites W1989686794 @default.
- W2037282693 cites W1990874027 @default.
- W2037282693 cites W1993321508 @default.
- W2037282693 cites W1997015167 @default.
- W2037282693 cites W1998956486 @default.
- W2037282693 cites W2000010668 @default.
- W2037282693 cites W2000365688 @default.
- W2037282693 cites W2001295176 @default.
- W2037282693 cites W2004057173 @default.
- W2037282693 cites W2014668131 @default.
- W2037282693 cites W2017969384 @default.
- W2037282693 cites W2018142060 @default.
- W2037282693 cites W2019370877 @default.
- W2037282693 cites W2024222597 @default.
- W2037282693 cites W2024612447 @default.
- W2037282693 cites W2029241783 @default.
- W2037282693 cites W2033673288 @default.
- W2037282693 cites W2035172708 @default.
- W2037282693 cites W2037422877 @default.
- W2037282693 cites W2043972985 @default.
- W2037282693 cites W2044763592 @default.
- W2037282693 cites W2044920983 @default.
- W2037282693 cites W2047435514 @default.
- W2037282693 cites W2048113251 @default.
- W2037282693 cites W2049143565 @default.
- W2037282693 cites W2050250997 @default.
- W2037282693 cites W2057670826 @default.
- W2037282693 cites W2062100812 @default.
- W2037282693 cites W2063487865 @default.
- W2037282693 cites W2066170978 @default.
- W2037282693 cites W2074034324 @default.
- W2037282693 cites W2075530756 @default.
- W2037282693 cites W2075547932 @default.
- W2037282693 cites W2083286034 @default.
- W2037282693 cites W2083350488 @default.
- W2037282693 cites W2085192898 @default.
- W2037282693 cites W2090218738 @default.
- W2037282693 cites W2090409233 @default.
- W2037282693 cites W2093434683 @default.
- W2037282693 cites W2093626408 @default.
- W2037282693 cites W2095101386 @default.
- W2037282693 cites W2096789907 @default.
- W2037282693 cites W2100025123 @default.
- W2037282693 cites W2109487451 @default.
- W2037282693 cites W2111894729 @default.
- W2037282693 cites W2112558157 @default.
- W2037282693 cites W2119184742 @default.
- W2037282693 cites W2126509509 @default.
- W2037282693 cites W2127383914 @default.
- W2037282693 cites W2128924239 @default.
- W2037282693 cites W2131413357 @default.
- W2037282693 cites W2137829703 @default.
- W2037282693 cites W2139863019 @default.
- W2037282693 cites W2142663753 @default.
- W2037282693 cites W2145626300 @default.
- W2037282693 cites W2147993894 @default.
- W2037282693 cites W2154224021 @default.
- W2037282693 cites W2155593243 @default.
- W2037282693 cites W2156939763 @default.
- W2037282693 cites W2162685508 @default.
- W2037282693 cites W2168905342 @default.
- W2037282693 cites W2171826294 @default.
- W2037282693 cites W2319961950 @default.
- W2037282693 cites W2322327164 @default.
- W2037282693 cites W2327094940 @default.
- W2037282693 cites W2332000490 @default.
- W2037282693 cites W2334168851 @default.
- W2037282693 cites W2949113491 @default.
- W2037282693 cites W2950384469 @default.
- W2037282693 cites W2950789259 @default.
- W2037282693 cites W2951449434 @default.
- W2037282693 cites W2952914620 @default.
- W2037282693 cites W2952979848 @default.
- W2037282693 cites W3004592377 @default.
- W2037282693 cites W3004647766 @default.