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- W2037294003 abstract "A new synthetic approach to silylated polyunsaturated halides has been developed, starting from the readily available (1E,3E)-1,4-bis(trimethylsilyl)-1,3-butadiene and (3E)-1,4-bis(trimethylsilyl)-3-buten-1-yne. A simple epoxidation reaction, followed by regioselective α-opening of the epoxide ring by metal halides affords the corresponding halohydrins with a high degree of stereoselectivity. A subsequent β-elimination reaction from these compounds leads to (Z,E)-dienyl halides and to (Z)-enyne halides." @default.
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- W2037294003 date "2001-01-01" @default.
- W2037294003 modified "2023-09-27" @default.
- W2037294003 title "A stereoselective synthesis of silylated polyunsaturated halides from α,β-epoxysilanes" @default.
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- W2037294003 doi "https://doi.org/10.1016/s0040-4020(00)01010-3" @default.
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