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- W2037322171 abstract "Abstract Radical polymerization of N-(2-methoxycarbonylphenyl)maleimide (2MCPhMI), N-(2-ethoxycarbonylphenyl)maleimide (2ECPhMI), and N-(2-n-butoxycarbonylphenyl)maleimide (2BCPhMI) was carried out in benzene at 60°C. The polymerization reactivity was examined as well as the solubility and the thermal properties of the resulting polymers. The effects of the alkyl groups in the 2-substituent on the reactivity and properties were discussed. Furthermore, the polymerization of 2BCPhMI was investigated kinetically in detail. It was revealed that the polymerization rate (R p) is represented by R p = k[2BCPhMI]0.84. [MAIB]0.88, where MAIB is dimethyl 2,2′-azobis(isobutyrate). The propagation and termination rate constants were determined for these polymerization systems by ESR method. The large reaction order with respect to the initiator concentration was interpreted by the termination rate constant depending on the initiator concentration." @default.
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- W2037322171 date "1996-08-01" @default.
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- W2037322171 title "Radical Polymerization ofN-(2-Alkoxycarbonylphenyl)Maleimides" @default.
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- W2037322171 doi "https://doi.org/10.1080/10601329608010904" @default.
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