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- W2037335957 abstract "Abstract : Real time surface enhanced Raman spectra have been obtained for thin films of buckminsterfullerene (C60) on gold in acetonitrile during cyclic voltammetric potential excursions. At potentials where neutral C60 is stable, all ten normally active Raman bands are observed, along with three weaker features that are infrared active in the bulk phase vibrational spectra. Upon electroreduction to the C60 monoanion, several Raman-active bands downshift significantly in frequency, most prominently for the Ag mode (1460 cm-1), which decreases by almost 20 cm-1. Additionally, several Hg bands become more intense, and in two cases yield doublets upon C60 formation, most probably reflecting a diminution in molecular symmetry." @default.
- W2037335957 created "2016-06-24" @default.
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- W2037335957 date "2010-08-22" @default.
- W2037335957 modified "2023-09-27" @default.
- W2037335957 title "ChemInform Abstract: Potential-Dependent Surface Raman Spectroscopy of Buckminsterfullerene Films on Gold: Vibrational Characteristics of Anionic versus Neutral C60." @default.
- W2037335957 cites W2951700538 @default.
- W2037335957 doi "https://doi.org/10.1002/chin.199211007" @default.
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