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- W2037337946 abstract "Abstract Angular dependence of light scattering from micellar solutions of dimethyloleylamine oxide has been measured in water and 10 −4 M NaCl at different micelle concentrations from the critical micelle concentration to 0.15 × 10 −2 g cm −3 . The angular dissymmetry is lower than unity and decreases with increasing micelle concentration. The observed angular dependence indicates stronger effect of external interference at higher micelle concentrations. The Zernike-Prins equation has been applied to derive the structure factor of micelles by separating the effect of external interference from that of internal interference and by choosing appropriate and consistent values of molecular weight and radius of gyration of micelles. The micelle size becomes larger by the addition of NaCl, and by an increase in micelle concentration. The micelle is rod-like but sufficiently flexible that it may be regarded as spherically symmetric. The radial distribution is obtained for the center of mass of a micelle, and, furthermore, the pair potential is derived by means of the Percus-Yevick equation or the Hypernetted Chain equation for the theory of simple liquids. The micelle molecular weight ranges from 370,000 to 1,030,000, depending on the condition, and, correspondingly, the radius of gyration changes from 213 to 300 A. The intermicellar interaction distance is located around 1300–1600 A." @default.
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- W2037337946 date "1984-04-01" @default.
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- W2037337946 title "Intermicellar correlation in light scattering from dilute micellar solutions of dimethyloleylamine oxide" @default.
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- W2037337946 doi "https://doi.org/10.1016/0021-9797(84)90160-7" @default.
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