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- W2037338362 abstract "The title compound [systematic name: 1-(2-deoxy-β-D- erythro -pentofuranosyl)-3-iodo-5-nitro-1 H -indole], C 13 H 13 IN 2 O 5 , exhibits an anti glycosylic bond conformation with a χ torsion angle of −114.9 (3)°. The furanose moiety shows a twisted C2′- endo sugar pucker ( S -type), with P = 141.3° and τ m = 40.3°. The orientation of the exocyclic C4′—C5′ bond is + ap ( gauche , trans ), with a γ torsion angle of 177.4 (2)°. The extended crystal structure is stabilized by hydrogen bonding and I...O contacts, as well as by stacking interactions. The O atoms of the nitro group act as acceptors, forming bifurcated hydrogen bonds within the ac plane. Additionally, the iodo substituent forms an interplanar contact with an O atom of the nitro group, and another contact with the O atom of the 5′-hydroxy group of the sugar moiety within the ac plane is observed. These contacts can be considered as the structure-determining factors for the molecular packing in the crystal structure." @default.
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- W2037338362 date "2009-02-21" @default.
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- W2037338362 title "The<i>N</i><sup>1</sup>-(2′-deoxyribofuranoside) of 3-iodo-5-nitroindole: a universal nucleoside forming nitro–iodo interactions" @default.
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- W2037338362 doi "https://doi.org/10.1107/s0108270109004673" @default.
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