FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2037360785> ?p ?o ?g. }

• W2037360785 endingPage "9871" @default.
• W2037360785 startingPage "9860" @default.
• W2037360785 abstract "The 1,4-dioxane derivative of cobalt bis(dicarbollide) reacts with dialkylsulfides and triphenylphosphine to give the corresponding sulfonium and phosphonium derivatives [8-L(CH2CH2O)2-3,3'-Co(1,2-C2B9H10)(1',2'-C2B9H11)] (L = SMe2, S(CH2CH2)2O, PPh3). The treatment of the triphenylphosphonium derivative with sodium hydroxide results in contraction of the side chain with formation of [8-HOCH2CH2O-3,3'-Co(1,2-C2B9H10)(1',2'-C2B9H11)](-). The same product was obtained by treatment of the dimethylsulfonium derivative with the poorly nucleophilic base t-BuOK, whereas the stronger nucleophiles induce the sulfur demethylation to give [8-MeS(CH2CH2O)2-3,3'-Co(1,2-C2B9H10)(1',2'-C2B9H11)](-). The alcohol was used for the synthesis of a series of other short-spacer functional derivatives [8-XOCH2CH2O-3,3'-Co(1,2-C2B9H10)(1',2'-C2B9H11)](-) (X = NH2, SH, N3). A similar contraction of the disclosed 1,4-dioxane ring via the reactions with SMe2 and PPh3 can be used for the synthesis of short-spacer functional derivatives of nido-carborane, whereas the 1,4-dioxane derivatives of closo-decaborate and closo-dodecaborate anions, being stronger electron donors, are more stable and do not react with dimethylsulfide and triphenylphosphine." @default.
• W2037360785 created "2016-06-24" @default.
• W2037360785 creator A5001570085 @default.
• W2037360785 creator A5037535752 @default.
• W2037360785 creator A5040798465 @default.
• W2037360785 creator A5049060369 @default.
• W2037360785 creator A5063803655 @default.
• W2037360785 creator A5064489929 @default.
• W2037360785 creator A5080425499 @default.
• W2037360785 date "2015-01-01" @default.
• W2037360785 modified "2023-10-12" @default.
• W2037360785 title "Cyanide free contraction of disclosed 1,4-dioxane ring as a route to cobalt bis(dicarbollide) derivatives with short spacer between the boron cage and terminal functional group" @default.
• W2037360785 cites W1969158727 @default.
• W2037360785 cites W1969813497 @default.
• W2037360785 cites W1985804695 @default.
• W2037360785 cites W1993930688 @default.
• W2037360785 cites W1996722229 @default.
• W2037360785 cites W2001936583 @default.
• W2037360785 cites W2004426025 @default.
• W2037360785 cites W2006857501 @default.
• W2037360785 cites W2012735102 @default.
• W2037360785 cites W2015342755 @default.
• W2037360785 cites W2017968968 @default.
• W2037360785 cites W2022073883 @default.
• W2037360785 cites W2024155505 @default.
• W2037360785 cites W2024630421 @default.
• W2037360785 cites W2024715800 @default.
• W2037360785 cites W2025085185 @default.
• W2037360785 cites W2026346763 @default.
• W2037360785 cites W2029162522 @default.
• W2037360785 cites W2029470012 @default.
• W2037360785 cites W2030462029 @default.
• W2037360785 cites W2039568596 @default.
• W2037360785 cites W2043900341 @default.
• W2037360785 cites W2043988530 @default.
• W2037360785 cites W2044404845 @default.
• W2037360785 cites W2046037596 @default.
• W2037360785 cites W2048687688 @default.
• W2037360785 cites W2049338463 @default.
• W2037360785 cites W2050732970 @default.
• W2037360785 cites W2051649380 @default.
• W2037360785 cites W2054072370 @default.
• W2037360785 cites W2055625721 @default.
• W2037360785 cites W2065995928 @default.
• W2037360785 cites W2069728471 @default.
• W2037360785 cites W2071011489 @default.
• W2037360785 cites W2072877023 @default.
• W2037360785 cites W2082332887 @default.
• W2037360785 cites W2084574784 @default.
• W2037360785 cites W2087241300 @default.
• W2037360785 cites W2093886437 @default.
• W2037360785 cites W2099798958 @default.
• W2037360785 cites W2101278909 @default.
• W2037360785 cites W2101301912 @default.
• W2037360785 cites W2102960769 @default.
• W2037360785 cites W2126795586 @default.
• W2037360785 cites W2135014518 @default.
• W2037360785 cites W2137138119 @default.
• W2037360785 cites W2141025463 @default.
• W2037360785 cites W2148127940 @default.
• W2037360785 cites W2149574085 @default.
• W2037360785 cites W2161018367 @default.
• W2037360785 cites W2169476619 @default.
• W2037360785 cites W2170585441 @default.
• W2037360785 cites W2171914066 @default.
• W2037360785 cites W2191500693 @default.
• W2037360785 cites W2322041419 @default.
• W2037360785 cites W2332851577 @default.
• W2037360785 cites W4229772442 @default.
• W2037360785 doi "https://doi.org/10.1039/c5dt01293g" @default.
• W2037360785 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25952990" @default.
• W2037360785 hasPublicationYear "2015" @default.
• W2037360785 type Work @default.
• W2037360785 sameAs 2037360785 @default.
• W2037360785 citedByCount "14" @default.
• W2037360785 countsByYear W20373607852016 @default.
• W2037360785 countsByYear W20373607852017 @default.
• W2037360785 countsByYear W20373607852018 @default.
• W2037360785 countsByYear W20373607852019 @default.
• W2037360785 countsByYear W20373607852020 @default.
• W2037360785 countsByYear W20373607852021 @default.
• W2037360785 countsByYear W20373607852022 @default.
• W2037360785 countsByYear W20373607852023 @default.
• W2037360785 crossrefType "journal-article" @default.
• W2037360785 hasAuthorship W2037360785A5001570085 @default.
• W2037360785 hasAuthorship W2037360785A5037535752 @default.
• W2037360785 hasAuthorship W2037360785A5040798465 @default.
• W2037360785 hasAuthorship W2037360785A5049060369 @default.
• W2037360785 hasAuthorship W2037360785A5063803655 @default.
• W2037360785 hasAuthorship W2037360785A5064489929 @default.
• W2037360785 hasAuthorship W2037360785A5080425499 @default.
• W2037360785 hasConcept C155647269 @default.
• W2037360785 hasConcept C161790260 @default.
• W2037360785 hasConcept C178790620 @default.
• W2037360785 hasConcept C178907741 @default.
• W2037360785 hasConcept C185592680 @default.
• W2037360785 hasConcept C2777247709 @default.
• W2037360785 hasConcept C2780707935 @default.

• next