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- W2037441451 abstract "Quantitative measurements of temperature-programmed reduction and oxidation (TPRTPO) at temperatures up to 1200 °C were used to characterize 2% metal on γ-alumina catalysts. The TPRTPO results were also compared with the redox behavior of the bulk compounds. It was found that supported Fe2O3, MoO3, WO3, and NiO could be reduced to metal only at temperatures near 1100 °C. In all cases reduction of supported oxides occurred at temperatures higher than those for the bulk oxides, indicating that interaction of the metal oxides with the support inhibited reduction. However, TPO of the supported metals usually occurred at a temperature lower than those for the bulk metals. This suggests that oxidation diminishes metal-support interaction and the higher rate of oxidation of supported metals reflects their smaller crystallite size. Chemisorption data are also given for the supported oxides after reduction at both moderate and high temperatures." @default.
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- W2037441451 date "1989-06-01" @default.
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- W2037441451 title "Temperature-programmed reduction and oxidation of metals supported on $gamma;-alumina" @default.
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- W2037441451 doi "https://doi.org/10.1016/0021-9517(89)90342-4" @default.
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