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- W2037454148 abstract "Abstract The thermoelastic properties and equation of state for liquids such as cyclopentane, tetramethylsilane and 2,3-dimethylbutane at high pressures and high temperatures have been analysed. The pressure dependences of thermal expansivity and isothermal compressibility have been determined for these liquids under pressure up to 100 MPa along different isotherms at selected temperatures in the range 208.0–298.15 K. We have formulated the pseudospinodal model for different liquids, along different isotherms for evaluating both thermal expansivity and isothermal compressibility with the change in pressure. It is found that the spinodal pressure is a characteristic property of the liquid depending only on temperature. The results obtained in this study are in good agreement with the experimental data reported in the literature. The plots between thermal expansivity versus pressure along different isotherms intersect each other for tetramethylsilane and 2,3-dimethylbutane. However, in the case of cyclopentane the plots do not intersect each other. Keywords: thermal expansivityisothermal compressibilitypseudospinodal modelsome organic liquidsPACS Nos: 62.50.+ P05.70. Ce Acknowledgements The authors are grateful to the reviewer for his helpful comments which have been used in revising the manuscript." @default.
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- W2037454148 date "2013-05-01" @default.
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- W2037454148 title "Analysis of thermoelastic properties and equation of state for cyclopentane, tetramethylsilane and 2,3-dimethylbutane" @default.
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- W2037454148 doi "https://doi.org/10.1080/00319104.2012.713551" @default.
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