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- W2037471504 abstract "A reusable dendritic catalyst ‘bottled’ in poly(p-xylene) (PPX) nanotubes is reported. The catalyst is synthesized by co-electrospinning poly(amidoamine) (PAMAM) dendrimers and poly(ethylene oxide) (PEO); the nanofibers are then coated with a PPX layer of [2.2]-para-cyclophane by chemical vapor deposition (CVD). A subsequent removal of the PEO core by extraction leaves the PAMAM dendrimers inside the PPX tubes. This new type of immobilized catalyst can catalyze Knoevenagel condensations in good yields. Catalyst recovery was readily achieved and could be reused for another nine runs without any loss in reactivity. The dendritic catalyst could be further functionalized by 2,2,6,6-tetramethylpiperidine-N-oxyl-radical (TEMPO) moieties. This catalyst was successfully studied in a TEMPO-mediated alcohol oxidation." @default.
- W2037471504 created "2016-06-24" @default.
- W2037471504 date "2009-12-21" @default.
- W2037471504 modified "2023-09-25" @default.
- W2037471504 title "Catalysts in a Bottle" @default.
- W2037471504 doi "https://doi.org/10.1055/s-0029-1218496" @default.
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