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- W2037472957 abstract "The rate of hydrolysis of methyl chloride, methyl bromide and methyl iodide have been measured in water over a wide range of temperature by a conductance method. The temperature dependence of the rate was shown to conform to an equation of the general form log 10 k = A/T + B log 10 T + C within experimental error. This implies that d∆ C p /d T = 0. By combining thermodynamic parameters derived from these data for the activation process with the corresponding terms for the gas-solution process and those for the gas phase, ‘absolute’ parameters for the transition state have been determined. A re-examination of the probable mechanism of hydrolysis is made in terms of a hypothetical gaseous ionization and the probable contribution of interaction of the water with the quasi-ionic transition state." @default.
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- W2037472957 date "1959-09-08" @default.
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- W2037472957 title "The neutral hydrolysis of the methyl halides" @default.
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- W2037472957 doi "https://doi.org/10.1098/rspa.1959.0152" @default.
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