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- W2037498429 endingPage "4684" @default.
- W2037498429 startingPage "4674" @default.
- W2037498429 abstract "The reaction of M(II) ions with azido ligands in the presence of different amino carboxylic acids gave four three-dimensional metal−azido coordination polymers, [Mn(3,5-daba)(N3)]n (1), [Cd(3,5-daba)(N3)]n (2; 3,5-daba = 3,5-diaminobenzoate), [Mn(4-aba)(N3)]n (3; 4-aba = 4-aminobenzoate), and [Cu2(gly)2(N3)2]n (4; gly = glycinate), which display different topological structures. Polymers 1 and 2 present 4,6-connected 3D networks with different Schläfli symbols. However, 3 and 4 feature an unprecedented trinodal 3,6-connected network with the Schläfli symbol (42.6)(4.62)(43.66.86) and an unusual 4-connected 3D net with the Lonsdaleite (hexagonal diamond) topology, respectively. Magnetic susceptibility measurements revealed dominant antiferromagnetic couplings for 1 and 3 and an overall dominant ferromagnetic coupling for 4, which presents metamagnetic behavior with a magnetic phase transition at a critical temperature of 6 K and a transition field of ca. 6030 Oe. The results demonstrate that the EE azido and syn−anti carboxylato bridges in our cases induce an antiferomagnetic interaction, and the anti−anti carboxylato bridge in 4 mediates a ferromagnetic interaction. The magnetic interaction through the EO azido bridge in 3 and 4 has a dependence on the value of the M−N−M bond angle." @default.
- W2037498429 created "2016-06-24" @default.
- W2037498429 creator A5011032994 @default.
- W2037498429 creator A5036940076 @default.
- W2037498429 creator A5060682672 @default.
- W2037498429 creator A5077691241 @default.
- W2037498429 creator A5083964094 @default.
- W2037498429 date "2009-04-21" @default.
- W2037498429 modified "2023-09-27" @default.
- W2037498429 title "Three-Dimensional Metal Azide Coordination Polymers with Amino Carboxylate Coligands: Synthesis, Structure, and Magnetic Properties" @default.
- W2037498429 cites W1899790140 @default.
- W2037498429 cites W1936274442 @default.
- W2037498429 cites W1965476260 @default.
- W2037498429 cites W1966445935 @default.
- W2037498429 cites W1970878474 @default.
- W2037498429 cites W1971025145 @default.
- W2037498429 cites W1974895338 @default.
- W2037498429 cites W1975141201 @default.
- W2037498429 cites W1975737352 @default.
- W2037498429 cites W1977335367 @default.
- W2037498429 cites W1978923134 @default.
- W2037498429 cites W1981210545 @default.
- W2037498429 cites W1983352627 @default.
- W2037498429 cites W1983499382 @default.
- W2037498429 cites W1986757683 @default.
- W2037498429 cites W1988349811 @default.
- W2037498429 cites W1999546410 @default.
- W2037498429 cites W2000536608 @default.
- W2037498429 cites W2000980125 @default.
- W2037498429 cites W2004209363 @default.
- W2037498429 cites W2007512432 @default.
- W2037498429 cites W2008721720 @default.
- W2037498429 cites W2010941430 @default.
- W2037498429 cites W2011204346 @default.
- W2037498429 cites W2012973360 @default.
- W2037498429 cites W2015353832 @default.
- W2037498429 cites W2019686748 @default.
- W2037498429 cites W2019975170 @default.
- W2037498429 cites W2020247553 @default.
- W2037498429 cites W2020510380 @default.
- W2037498429 cites W2020676845 @default.
- W2037498429 cites W2021763760 @default.
- W2037498429 cites W2025948275 @default.
- W2037498429 cites W2029071538 @default.
- W2037498429 cites W2029721190 @default.
- W2037498429 cites W2030411384 @default.
- W2037498429 cites W2031550584 @default.
- W2037498429 cites W2032246515 @default.
- W2037498429 cites W2034676439 @default.
- W2037498429 cites W2035653459 @default.
- W2037498429 cites W2036115336 @default.
- W2037498429 cites W2037846035 @default.
- W2037498429 cites W2037897229 @default.
- W2037498429 cites W2038040012 @default.
- W2037498429 cites W2038253464 @default.
- W2037498429 cites W2039035680 @default.
- W2037498429 cites W2043349031 @default.
- W2037498429 cites W2044562528 @default.
- W2037498429 cites W2044564556 @default.
- W2037498429 cites W2044701744 @default.
- W2037498429 cites W2044814053 @default.
- W2037498429 cites W2044979436 @default.
- W2037498429 cites W2046794213 @default.
- W2037498429 cites W2049398046 @default.
- W2037498429 cites W2050473096 @default.
- W2037498429 cites W2053568623 @default.
- W2037498429 cites W2055070786 @default.
- W2037498429 cites W2056707510 @default.
- W2037498429 cites W2057874777 @default.
- W2037498429 cites W2060682046 @default.
- W2037498429 cites W2061344794 @default.
- W2037498429 cites W2061709672 @default.
- W2037498429 cites W2064110899 @default.
- W2037498429 cites W2071236931 @default.
- W2037498429 cites W2071655492 @default.
- W2037498429 cites W2071751209 @default.
- W2037498429 cites W2073116823 @default.
- W2037498429 cites W2076045708 @default.
- W2037498429 cites W2078834111 @default.
- W2037498429 cites W2080534794 @default.
- W2037498429 cites W2080665513 @default.
- W2037498429 cites W2083046671 @default.
- W2037498429 cites W2083315581 @default.
- W2037498429 cites W2083650897 @default.
- W2037498429 cites W2086624247 @default.
- W2037498429 cites W2087936754 @default.
- W2037498429 cites W2089796724 @default.
- W2037498429 cites W2090137579 @default.
- W2037498429 cites W2091177197 @default.
- W2037498429 cites W2092408749 @default.
- W2037498429 cites W2093328051 @default.
- W2037498429 cites W2093411968 @default.
- W2037498429 cites W2093512382 @default.
- W2037498429 cites W2095575229 @default.
- W2037498429 cites W2099426913 @default.
- W2037498429 cites W2103314657 @default.
- W2037498429 cites W2105687411 @default.
- W2037498429 cites W2110241495 @default.