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- W2037503722 endingPage "8195" @default.
- W2037503722 startingPage "8191" @default.
- W2037503722 abstract "Activated and deactivated aryl and heteroaryl chlorides are efficiently cross-coupled with potassium vinyl- and alkenyltrifluoroborates using 4-hydroxyacetophenone oxime derived palladacycle as precatalyst in 1 to 3 mol % Pd loading, Binap as ligand, and Cs2CO3 as base in DMF at 120 °C. The reactions can also be performed using Pd(OAc)2 as Pd(0) source, although with lower efficiency. Bidentate ligands such as Binap and dppp can be used, the former being the best choice. Only in the case of deactivated aryl chlorides should the reaction temperature be increased to 160 °C to achieve good yields. The corresponding cross-coupled compounds, such as styrenes, stilbenes, and alkenylarenes, are obtained in good yields and with high regio- and diastereoselectivity." @default.
- W2037503722 created "2016-06-24" @default.
- W2037503722 creator A5015456687 @default.
- W2037503722 creator A5042906839 @default.
- W2037503722 date "2009-10-02" @default.
- W2037503722 modified "2023-10-17" @default.
- W2037503722 title "General Reaction Conditions for the Palladium-Catalyzed Vinylation of Aryl Chlorides with Potassium Alkenyltrifluoroborates" @default.
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- W2037503722 doi "https://doi.org/10.1021/jo901681s" @default.
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