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- W2037516110 abstract "Abstract A high-resolution infrared spectrum of DCCI has been measured in the regions of the bands of 2ν1, ν1+ν2, ν2+ν3, ν2+ν4, ν2+ν5, and ν4+ν5. Using these bands together with the spectra measured previously, the rovibrational states of 2ν1, ν1+ν2, ν1+ν3, ν1+ν4, ν1+ν5, ν1+2ν5, ν2+ν3, ν2+ν4, ν2+ν5, ν2+2ν5, ν3+ν4, ν4+ν5, and ν4+2ν5 have been analyzed. Various l-type and Fermi resonances have been taken into account in the analysis. In addition, the weak Coriolis resonance between the levels υ3=υ4=1 and υ4=2 has been considered. Accurate values for the molecular constants and the appropriate resonance parameters have been obtained. The unperturbed normal vibrational frequencies associated to the equilibrium state have been calculated for both isotopic species HCCI and DCCI. Then the harmonic force constants for monoiodoacetylene have been determined." @default.
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- W2037516110 date "2004-07-01" @default.
- W2037516110 modified "2023-10-14" @default.
- W2037516110 title "High-resolution infrared study on DCCI: harmonic force field of monoiodoacetylene" @default.
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- W2037516110 doi "https://doi.org/10.1016/j.jms.2004.03.007" @default.
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