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• W2037531712 abstract "From quasielastic neutron scattering experiments performed in the rotator phase of n-alkanes (CnH2n+2), as a function of both n and temperature, two types of rotational diffusion have been detected. Type B corresponds to a uniform rotational diffusion, whereas type A corresponds to a hindered rotation, probably limited to large amplitude oscillations. It is the first time that type A rotational diffusion, given by the orthorhombic symmetry phase RI, is observed. On increasing the temperature it rapidly evolves towards the type B diffusion. Correlation times τ which seem to be rather independent of the phase type are of the order of 5×10−12 s." @default.
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• W2037531712 date "1984-12-01" @default.
• W2037531712 modified "2023-10-11" @default.
• W2037531712 title "Rotational diffusion in the rotator phase of <i>n</i>-alkanes" @default.
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• W2037531712 doi "https://doi.org/10.1063/1.447491" @default.
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