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- W2037556987 abstract "A photoinduced procedure for the intermolecular hydroamination of alkenes using azoles is described. This reaction occurs in modest to good yield for 6- and 7-membered cyclic alkenes. Upon irradiation at 254 nm in the presence of methyl benzoate and a small amount of triflic acid as an additive (20 mol %), imidazoles, pyrazoles, triazoles, and tetrazole can react with the alkene to afford complex Markovnikov adducts. The proposed mechanism involves photoisomerization to generate highly strained (E)-cycloalkene intermediates and (E)-cycloalkene protonation followed by reaction with the azole nucleophile. Alkene isomerization was found to be a competing side reaction under these conditions." @default.
- W2037556987 created "2016-06-24" @default.
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- W2037556987 date "2008-05-27" @default.
- W2037556987 modified "2023-09-26" @default.
- W2037556987 title "ChemInform Abstract: Intermolecular Hydroaminations via Strained (E)-Cycloalkenes." @default.
- W2037556987 cites W2951744163 @default.
- W2037556987 doi "https://doi.org/10.1002/chin.200822042" @default.
- W2037556987 hasPublicationYear "2008" @default.
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