Matches in SemOpenAlex for { <https://semopenalex.org/work/W2037559306> ?p ?o ?g. }
Showing items 1 to 68 of
68
with 100 items per page.
- W2037559306 endingPage "1190" @default.
- W2037559306 startingPage "1185" @default.
- W2037559306 abstract "Durch Kombination von DTA/TG, Hochtemperatur-Guinier-Simon-Aufnahmen und präparativen Methoden, sowie durch Charakterisierung der Edukte, Intermediate und Produkte mittels Röntgenaufnahmen nach dem Guinier-Verfahren und anhand von IR-Spektren, wurde der „thermische Abbau”︁ von Edelmetallverbindungen eingehend untersucht: (NH4)2[PtCl6], (NH4)2[PtCl4], [Pt(NH3)4][PtCl4], [Pt(NH3)4]Cl2 und trans-[Pt(NH3)2Cl2]; (NH4)2[PdCl4], [Pd(NH3)4]Cl2, trans-[Pd(NH3)2Cl2] und [Pd(NH3)4][PdCl4]; (NH4)2[RhCl5(H2O)], (NH4)3[Rh2Cl9], K2[RhCl5(H2O)] und K2[RhCl5(NH3)]; (NH4)2[RuCl5(NH3)] und (NH4)4[Ru2Cl10O] Der entscheidende Schritt des Mechanismus des „thermischen Abbaus”︁ ist die „innere”︁ Reduktion des Edelmetallkations durch den Amminstickstoff. On the Mechanism of the Thermal Decomposition of Ammonium and Ammin Chloro Complexes of Ruthenium, Rhodium, Palladium and Platinum The thermolysis of noble metal compounds was investigated by a combination of independent physical (DTA/TG, high-temperature Guinier-Simon-technique) and preparative methods, characterization of the educts, intermediats and products by Guinier X-ray patterns and IR spectroscopy: (NH4)2[PtCl6], (NH4)2[PtCl4], [Pt(NH3)4][PtCl4], [Pt(NH3)4]Cl2, and trans-[Pt(NH3)2Cl2]; (NH4)2[PdCl4], [Pd(NH3)4]Cl2, trans-[Pd(NH3)2Cl2], and [Pd(NH3)4][PdCl4]; (NH4)2[RhCl5(H2O)], (NH4)3[Rh2Cl9], K2[RhCl5(H2O)], and K2[RhCl5(NH3)]; (NH4)2[RuCl5(NH3)] and (NH4)4[Ru2Cl10O] The most important step of the mechanism of the thermal decomposition is the „internal”︁ redox reaction between the noble metal cation and the nitrogen atom of the ammine ligand." @default.
- W2037559306 created "2016-06-24" @default.
- W2037559306 creator A5045715383 @default.
- W2037559306 creator A5068165268 @default.
- W2037559306 date "1994-07-01" @default.
- W2037559306 modified "2023-10-18" @default.
- W2037559306 title "Zum Mechanismus des thermischen Abbaus von Ammonium- und Ammin-Chlorokomplexen des Rutheniums, Rhodiums, Palladiums und Platins" @default.
- W2037559306 cites W1521159998 @default.
- W2037559306 cites W1540405481 @default.
- W2037559306 cites W1859648981 @default.
- W2037559306 cites W2001888178 @default.
- W2037559306 cites W2036963839 @default.
- W2037559306 cites W2048265046 @default.
- W2037559306 cites W2065913886 @default.
- W2037559306 cites W2070708028 @default.
- W2037559306 cites W2083611046 @default.
- W2037559306 cites W2953034999 @default.
- W2037559306 cites W3138630252 @default.
- W2037559306 doi "https://doi.org/10.1002/zaac.19946200710" @default.
- W2037559306 hasPublicationYear "1994" @default.
- W2037559306 type Work @default.
- W2037559306 sameAs 2037559306 @default.
- W2037559306 citedByCount "7" @default.
- W2037559306 countsByYear W20375593062018 @default.
- W2037559306 countsByYear W20375593062020 @default.
- W2037559306 countsByYear W20375593062021 @default.
- W2037559306 crossrefType "journal-article" @default.
- W2037559306 hasAuthorship W2037559306A5045715383 @default.
- W2037559306 hasAuthorship W2037559306A5068165268 @default.
- W2037559306 hasConcept C124681953 @default.
- W2037559306 hasConcept C155647269 @default.
- W2037559306 hasConcept C160434732 @default.
- W2037559306 hasConcept C161790260 @default.
- W2037559306 hasConcept C178790620 @default.
- W2037559306 hasConcept C185592680 @default.
- W2037559306 hasConcept C2779870022 @default.
- W2037559306 hasConcept C518104683 @default.
- W2037559306 hasConcept C544153396 @default.
- W2037559306 hasConceptScore W2037559306C124681953 @default.
- W2037559306 hasConceptScore W2037559306C155647269 @default.
- W2037559306 hasConceptScore W2037559306C160434732 @default.
- W2037559306 hasConceptScore W2037559306C161790260 @default.
- W2037559306 hasConceptScore W2037559306C178790620 @default.
- W2037559306 hasConceptScore W2037559306C185592680 @default.
- W2037559306 hasConceptScore W2037559306C2779870022 @default.
- W2037559306 hasConceptScore W2037559306C518104683 @default.
- W2037559306 hasConceptScore W2037559306C544153396 @default.
- W2037559306 hasIssue "7" @default.
- W2037559306 hasLocation W20375593061 @default.
- W2037559306 hasOpenAccess W2037559306 @default.
- W2037559306 hasPrimaryLocation W20375593061 @default.
- W2037559306 hasRelatedWork W1967400304 @default.
- W2037559306 hasRelatedWork W1997864104 @default.
- W2037559306 hasRelatedWork W2007844853 @default.
- W2037559306 hasRelatedWork W2009865269 @default.
- W2037559306 hasRelatedWork W2031371724 @default.
- W2037559306 hasRelatedWork W2047390666 @default.
- W2037559306 hasRelatedWork W2105613033 @default.
- W2037559306 hasRelatedWork W2165335920 @default.
- W2037559306 hasRelatedWork W2364453979 @default.
- W2037559306 hasRelatedWork W231988658 @default.
- W2037559306 hasVolume "620" @default.
- W2037559306 isParatext "false" @default.
- W2037559306 isRetracted "false" @default.
- W2037559306 magId "2037559306" @default.
- W2037559306 workType "article" @default.