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- W2037561812 abstract "In the Rh4(CO)12-catalyzed hydroformylation of the vinylpyridine isomers, a very different chemoselectivity between 3- and 4-vinylpyridine is observed: whereas the former is fully transformed into the corresponding branched aldehyde, the latter only undergoes hydrogenation to 4-ethylpyridine. A different behavior of the corresponding branched alkylmetal intermediates related to the different polarization of the Rh−C bond has been suggested to explain the above results." @default.
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- W2037561812 date "1998-04-21" @default.
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- W2037561812 title "Opposite Chemoselectivity (Hydrogenation versus Carbonylation) Shown by 4-Vinylpyridine with Respect to 3-Vinylpyridine under Hydroformylation Conditions with Rh<sub>4</sub>(CO)<sub>12</sub>" @default.
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- W2037561812 doi "https://doi.org/10.1021/om970517s" @default.
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