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- W2037564344 abstract "A bisphthalocyanine lutetium derivative substituted with benzo-15-crown-5 subunits, [(15C5)4Pc]2Lu (1), has been shown to form sandwich complexes with cations such as potassium ion, the complexes further form pillarlike aggregates. Light scattering studies have been carried out as a function of the ratio [K+]/[1] in order to determine the characteristics of the aggregates. It has been demonstrated that high molar mass aggregates (M̄w about 106) are formed even at small [K+]/[1] ratios, they coexist with uncomplexed monomeric [(15C5)4Pc]2Lu. The transformation from the metal-free monomer to the metal ion-containing aggregate involves a highly nonlinear two-stage complexation process. The shape of the aggregate is very probably rodlike (pillar-type structure) as indicated by the angle dependence of the light scattered." @default.
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- W2037564344 date "1997-10-01" @default.
- W2037564344 modified "2023-10-14" @default.
- W2037564344 title "Ionoelectronics. Pillarlike Aggregates Formed via Highly Nonlinear Complexation Processes. A Light-Scattering Study" @default.
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- W2037564344 doi "https://doi.org/10.1021/ja9644438" @default.
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