Matches in SemOpenAlex for { <https://semopenalex.org/work/W2037581237> ?p ?o ?g. }
- W2037581237 abstract "The phase behavior of charge-stabilized colloidal suspensions is modeled by a combination of response theory for electrostatic interparticle interactions and variational theory for free energies. Integrating out degrees of freedom of the microions (counterions, salt ions), the macroion-microion mixture is mapped onto a one-component system governed by effective macroion interactions. Linear response of microions to the electrostatic potential of the macroions results in a screened-Coulomb (Yukawa) effective pair potential and a one-body volume energy, while nonlinear response modifies the effective interactions [A. R. Denton, Phys. Rev. E 70, 031404 (2004)]. The volume energy and effective pair potential are taken as input to a variational free energy, based on thermodynamic perturbation theory. For both linear and first-order nonlinear effective interactions, a coexistence analysis applied to aqueous suspensions of highly charged macroions and monovalent microions yields bulk separation of macroion-rich and macroion-poor phases below a critical salt concentration, in qualitative agreement with predictions of related linearized theories [R. van Roij, M. Dijkstra, and J.-P. Hansen, Phys. Rev. E 59, 2010 (1999); P. B. Warren, J. Chem. Phys. 112, 4683 (2000)]. It is concluded that nonlinear screening can modify phase behavior but does not necessarily suppress bulk phase separation of de-ionized suspensions." @default.
- W2037581237 created "2016-06-24" @default.
- W2037581237 creator A5041149702 @default.
- W2037581237 date "2006-04-24" @default.
- W2037581237 modified "2023-09-26" @default.
- W2037581237 title "Phase separation in charge-stabilized colloidal suspensions: Influence of nonlinear screening" @default.
- W2037581237 cites W1132509035 @default.
- W2037581237 cites W1966696598 @default.
- W2037581237 cites W1969739520 @default.
- W2037581237 cites W1970160072 @default.
- W2037581237 cites W1974391939 @default.
- W2037581237 cites W1976007034 @default.
- W2037581237 cites W1976397099 @default.
- W2037581237 cites W1977707378 @default.
- W2037581237 cites W1983966894 @default.
- W2037581237 cites W1989683268 @default.
- W2037581237 cites W1990235733 @default.
- W2037581237 cites W1990708615 @default.
- W2037581237 cites W1994029378 @default.
- W2037581237 cites W1995915338 @default.
- W2037581237 cites W1996404652 @default.
- W2037581237 cites W1996554864 @default.
- W2037581237 cites W1997359597 @default.
- W2037581237 cites W1998193423 @default.
- W2037581237 cites W1999064130 @default.
- W2037581237 cites W1999188537 @default.
- W2037581237 cites W2000989546 @default.
- W2037581237 cites W2001537328 @default.
- W2037581237 cites W2003312209 @default.
- W2037581237 cites W2005760845 @default.
- W2037581237 cites W2006130740 @default.
- W2037581237 cites W2007154828 @default.
- W2037581237 cites W2007843563 @default.
- W2037581237 cites W2009348809 @default.
- W2037581237 cites W2011794432 @default.
- W2037581237 cites W2011957182 @default.
- W2037581237 cites W2014428300 @default.
- W2037581237 cites W2020183368 @default.
- W2037581237 cites W2022840857 @default.
- W2037581237 cites W2023391815 @default.
- W2037581237 cites W2023773560 @default.
- W2037581237 cites W2030327996 @default.
- W2037581237 cites W2030966676 @default.
- W2037581237 cites W2031758447 @default.
- W2037581237 cites W2033156442 @default.
- W2037581237 cites W2034669546 @default.
- W2037581237 cites W2037879531 @default.
- W2037581237 cites W2038418372 @default.
- W2037581237 cites W2038644200 @default.
- W2037581237 cites W2039569086 @default.
- W2037581237 cites W2042884243 @default.
- W2037581237 cites W2043341935 @default.
- W2037581237 cites W2045302866 @default.
- W2037581237 cites W2046242603 @default.
- W2037581237 cites W2046611731 @default.
- W2037581237 cites W2047041811 @default.
- W2037581237 cites W2054967121 @default.
- W2037581237 cites W2056972872 @default.
- W2037581237 cites W2057491657 @default.
- W2037581237 cites W2058045505 @default.
- W2037581237 cites W2059208722 @default.
- W2037581237 cites W2059523289 @default.
- W2037581237 cites W2060061805 @default.
- W2037581237 cites W2061799556 @default.
- W2037581237 cites W2064930022 @default.
- W2037581237 cites W2065078143 @default.
- W2037581237 cites W2066535312 @default.
- W2037581237 cites W2066762673 @default.
- W2037581237 cites W2067017429 @default.
- W2037581237 cites W2069505941 @default.
- W2037581237 cites W2072348763 @default.
- W2037581237 cites W2074865683 @default.
- W2037581237 cites W2076762290 @default.
- W2037581237 cites W2076822641 @default.
- W2037581237 cites W2077778624 @default.
- W2037581237 cites W2077809249 @default.
- W2037581237 cites W2081901506 @default.
- W2037581237 cites W2085234413 @default.
- W2037581237 cites W2086545139 @default.
- W2037581237 cites W2086698089 @default.
- W2037581237 cites W2088133397 @default.
- W2037581237 cites W2092340579 @default.
- W2037581237 cites W2093004952 @default.
- W2037581237 cites W2096753384 @default.
- W2037581237 cites W2100432652 @default.
- W2037581237 cites W2103543844 @default.
- W2037581237 cites W2108205854 @default.
- W2037581237 cites W2115011796 @default.
- W2037581237 cites W2115946882 @default.
- W2037581237 cites W2118301109 @default.
- W2037581237 cites W2125107447 @default.
- W2037581237 cites W2134172817 @default.
- W2037581237 cites W2134228288 @default.
- W2037581237 cites W2138865905 @default.
- W2037581237 cites W2163448702 @default.
- W2037581237 cites W2963050658 @default.
- W2037581237 cites W3098084504 @default.
- W2037581237 cites W3101243211 @default.
- W2037581237 cites W3105298920 @default.
- W2037581237 cites W4248204473 @default.