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- W2037597777 abstract "Thin Pd–Ru deposits with 90–100% Pd in the bulk were obtained electrochemically from the mixtures of PdCl2 and RuCl3 aqueous solutions. Hydrogen absorption in Pd–Ru deposits was performed using cyclic voltammetry and chronoamperometry from 0.5 H2SO4 solutions at room temperature. Pd–Ru electrodeposits with a high Pd bulk content (above 97%) can absorb more hydrogen than pure Pd, with the hydrogen-to-metal atomic ratio up to 0.85 (as compared with 0.74 for Pd). The absorption capacity of Pd–Ru electrodes containing less than 97% Pd gradually decreases and the H/M ratio drops to ca. 0.50 for electrodes with 90% Pd. With increasing Ru content the potential corresponding to the α- and β-phase transition is shifted negatively with respect to that for pure Pd. Hydrogen absorption properties of Pd–Ru electrodes may be explained taking into account changes in electronic structure probably resulting from alloy formation between Pd and Ru." @default.
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- W2037597777 date "2012-07-01" @default.
- W2037597777 modified "2023-09-26" @default.
- W2037597777 title "Pd–Ru electrodeposits with high hydrogen absorption capacity" @default.
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- W2037597777 doi "https://doi.org/10.1016/j.elecom.2012.04.022" @default.
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