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• W2037607519 abstract "Abstract A new zirconium complex containing amidinate, guanidinate and amide ligand sets with formula Zr[(CyN)2CMe][(CyN)2CNMe2](NMe2)2 (1) (Cy = cyclohexyl) was synthesized by the insertion of the 1,3-dicyclohexylcarbodiimide moiety into the bond of zirconium and dimethylamido group. Characterization of the complex 1 was achieved using elemental analysis, 1H and 13C NMR spectra and single crystal X-ray diffraction. The molecular structure of the complex 1 revealed that the coordination geometry around the zirconium is a distorted pseudo-octahedron. The metal center is surrounded by the four nitrogen atoms of two bidentate amidinate and guanidinate ligands positioned cis to each other and two cis-NMe2 groups." @default.
• W2037607519 created "2016-06-24" @default.
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• W2037607519 date "2009-08-01" @default.
• W2037607519 modified "2023-09-26" @default.
• W2037607519 title "Synthesis, characterization and crystal structure of zirconium complex containing amidinate, guanidinate and amide ligand sets" @default.
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• W2037607519 doi "https://doi.org/10.1016/j.ica.2009.05.049" @default.
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