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- W2037623369 abstract "Transient free radicals in the magnetic field‐dependent photoreduction of quinones (menadione or anthraquinone) in a sodium dodecyl sulfate (SDS) micellar solution, were converted to stable nitroxide radicals by the ‘‘spin trapping’’ technique with or without the microwave irradiation. Upon irradiating the microwave at 160 mW, the product yield (‘‘spin adduct’’ of the alkyl radical generated from SDS molecule) decreased by up to 14% at certain magnetic fields in a resonant manner. Although only one component of the postulated radical pair was converted to the spin adduct, the decrease in the yield as a function of external magnetic field revealed the ESR spectra of both component radicals of the radical pair, i.e., the semiquinone radical and the alkyl radical from SDS. This experiment not only gives the direct evidence for the radical pair model, but also suggests the possibility for this method to be applied in controlling the chemical reactions by the microwave. A simple calculation was made to simulate the observed ‘‘product yield‐detected ESR.’’ Agreements were achieved semiquantitatively between the observed reductions in the spin adduct yields and those calculated. The estimated exchange interaction between the component radicals in the radical pair of the present systems was lower than 0.3 mT." @default.
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- W2037623369 date "1987-06-15" @default.
- W2037623369 modified "2023-10-18" @default.
- W2037623369 title "Product yield‐detected ESR on magnetic field‐dependent photoreduction of quinones in SDS micellar solution" @default.
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- W2037623369 doi "https://doi.org/10.1063/1.452378" @default.
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