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• W2037632493 abstract "Photolysis of an allal C-3 azidoformate provoked intramolecular nitrene insertion into the glycal CC unit and allowed direct incorporation of alcohol nucleophiles as β-disposed substituents at C-1. The 2-amido allopyranoside products were elaborated via N-acylation and selective oxazolidinone hydrolysis, providing N-Boc-protected 2-amino sugars and simplifying stereochemical assignments. Synthesis of the potentially labile allal azidoformate was achieved via reaction of the corresponding carbonyl imidazolide with trimethylsilyl azide, facilitated by dibutyltin oxide." @default.
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• W2037632493 date "2001-01-12" @default.
• W2037632493 modified "2023-10-15" @default.
• W2037632493 title "Photo Amidoglycosylation of an Allal Azidoformate. Synthesis of <i>β</i>-2-Amido Allopyranosides" @default.
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• W2037632493 doi "https://doi.org/10.1021/ol0069002" @default.
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