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- W2037637839 abstract "Abstract A hectorite clay intersalation 2 compound containing interlayered Ni(phen)32+/SO42− ion pairs is shown to be a selective catalyst for the conversion of alkyl bromides to the corresponding chlorides by reaction with NaCl under triphase (liquid-liquid-solid) conditions. In contrast, Ni(phen)32+ salts alone are poor phase transfer catalysts for reactions involving anionic nucleophiles, as are the homoionic Ni(phen)32+ and Na+-exchanged forms of the mineral. The intercalation compound is forty times more selective for the reaction of normal-chain butyl bromide than branched-chain 3,5,5-tri-methylhexyl bromide. Selective adsorption based on size or polarity appears to contribute to the dramatic enhancement in substrate selectivity relative to conventional liquid-liquid phase transfer catalysts." @default.
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- W2037637839 date "1983-10-01" @default.
- W2037637839 modified "2023-09-26" @default.
- W2037637839 title "Clay intersalation compounds for selective triphase catalysis: Reaction of alkyl bromides with NaCl" @default.
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- W2037637839 doi "https://doi.org/10.1016/0304-5102(93)80114-a" @default.
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