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- W2037641861 abstract "This paper describes a total synthesis of a biogenetically possible, hitherto unknown macrolide 4. Starting with 3,5-dimethoxybenzaldehyde, ketone 5a was generated in five steps. Alkylation of this compound by bromopentene followed by decarboxylation yielded pentenyl ketone 6. Oxymercuration–demercuration followed by dehydration gave cyclic enol ether 8. Oxidation with m-chloroperbenzoic acid led to the macrolide 4." @default.
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- W2037641861 date "1968-10-01" @default.
- W2037641861 modified "2023-10-10" @default.
- W2037641861 title "Total synthesis of a curvularin isomer" @default.
- W2037641861 doi "https://doi.org/10.1139/v68-517" @default.
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