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• W2037644554 startingPage "6401" @default.
• W2037644554 abstract "Scanning electrochemical microscopy (SECM) was used to study the kinetics of hydrogen oxidation on platinum, iridium, and rhodium substrates in acidic media. Hydrogen was generated at a platinum tip by reduction of H+ and oxidized at a Pt, Ir, or Rh substrate. The Tafel slope (117 mV, corresponding to a transfer coefficient, α, of 0.50) and the rate constant for hydrogen oxidation on Pt obtained by fitting approach curves (0.22 cm/s at the halfwave potential) agree with a previous SECM result. Kinetic data were also obtained on Ir (Tafel slope = 113 mV, k° = 0.25 cm/s, α = 0.48), and Rh (Tafel slope = 138 mV, k° = 0.010 cm/s, α = 0.58) substrates. These results demonstrate that hydrogen oxidation on Pt and Ir occurs at a similar rate, but is much slower on Rh." @default.
• W2037644554 created "2016-06-24" @default.
• W2037644554 creator A5070242592 @default.
• W2037644554 date "2003-06-05" @default.
• W2037644554 modified "2023-10-03" @default.
• W2037644554 title "Scanning Electrochemical Microscopy: Investigation of Hydrogen Oxidation at Polycrystalline Noble Metal Electrodes" @default.
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• W2037644554 doi "https://doi.org/10.1021/jp027436g" @default.
• W2037644554 hasPublicationYear "2003" @default.
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