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- W2037646940 abstract "The selenite radical, SeO3-, has been found to selectively produce the cytosyl radical upon one-electron oxidation of duplex DNA. This is at first a surprising result as SeO3- can only oxidize guanine of the DNA bases, implying that the transiently formed guanyl radical cation must transpose into the neutral cytosyl radical with loss of a proton. Back oxidation to produce the neutral guanyl radical, in competition with another fixation reaction, is observed." @default.
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- W2037646940 date "2006-11-23" @default.
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- W2037646940 title "Cytosine-Gated Hole Creation and Transfer in DNA in Aqueous Solution" @default.
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- W2037646940 doi "https://doi.org/10.1021/ja0658416" @default.
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