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- W2037669690 abstract "A new stilbene-containing amphiphile with the chromophore in the hydrophilic headgroup was synthesized, and the photoisomerization of the stilbene sulfonate was investigated at the air-water interface. It could be shown that the isomerization leads to a decrease in area per molecule. The binding of inorganic and organic cations from the subphase occurs in the nanomolar concentration range. Binding was verified by UV and fluorescence spectroscopy and by electron spectroscopy for chemical analysis. Upon complexation with alkaline earth metals, the stilbene photoisomerization proceeds apparently faster, whereas organic cations of the viologen type quench the photoreaction. This is the first example of a control of photoisomerization in monolayers by cation complexation." @default.
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- W2037669690 date "1997-06-01" @default.
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- W2037669690 title "Photochemistry in stilbene-containing monolayers. Part II: effect of cation binding on photoisomerization" @default.
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- W2037669690 doi "https://doi.org/10.1016/s0927-7757(96)03965-9" @default.
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