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• W2037678229 abstract "The effect of the average $R$-site ionic radius $⟨mathrm{IR}⟩$ and variance on the orbital and magnetic order in ${R}^{3+}$-doped ${mathrm{YVO}}_{3}$ was studied in ${mathrm{Y}}_{1ensuremath{-}x}{mathrm{La}}_{x}{mathrm{VO}}_{3}$ and ${mathrm{Y}}_{1ensuremath{-}x}({mathrm{La}}_{0.2337}{mathrm{Lu}}_{0.7663}{)}_{x}{mathrm{VO}}_{3}$ with fixed $⟨mathrm{IR}⟩$. The orbital flipping temperature ${T}_{CG}$ increases nonlinearly with increasing $R$-site variance, indicating that the V-O-V bond angle is not the primary driving force stabilizing the $C$-type orbitally ordered phase. The suppressed thermal conductivity in the $G$-type orbitally ordered phase signals some remaining orbital randomness that is enhanced by ${t}^{2}$ and et hybridization in $^{3}T_{1g}$ site symmetry." @default.
• W2037678229 created "2016-06-24" @default.
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• W2037678229 date "2007-11-08" @default.
• W2037678229 modified "2023-10-16" @default.
• W2037678229 title "Orbital Fluctuations and Orbital Flipping in<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mi>R</mml:mi><mml:msub><mml:mi>VO</mml:mi><mml:mn>3</mml:mn></mml:msub></mml:math>Perovskites" @default.
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• W2037678229 doi "https://doi.org/10.1103/physrevlett.99.197201" @default.
• W2037678229 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18233108" @default.
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