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- W2037690410 abstract "An industrial desulphurization process is modelled on the basis of equilibrium data, mass balance, mass transfer and plant data. For the Ca2+–SO2–H2O system the equilibrium diagram at 25°C is constructed. The diagram presents the concentration of total SO2 combined SO2, true free SO2, the pH value and the solubility curve for CaSO3.1/2H2O. Besides the basic chemistry occuring in the process, the role of relevant additional chemical species is explained. The overall desulphurization process is studied through the analysis of the partial processes: absorption of SO2 and sulphite to bisulphite reaction; limestone dissolution and its reaction with Ca(HSO3)2; absorption of O2, oxidation of CaSO3 and gypsum crystallization mass balance and the mass transfer. The model is tested on the basis of data taken from an industrial plant." @default.
- W2037690410 created "2016-06-24" @default.
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- W2037690410 date "2004-09-01" @default.
- W2037690410 modified "2023-10-01" @default.
- W2037690410 title "Equilibrium and Mass Transfer in the Ca2+–SO2–H2O System for the Analysis of the Flue Gas Desulphurization Process" @default.
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- W2037690410 doi "https://doi.org/10.1205/psep.82.5.371.44188" @default.
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