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- W2037700187 abstract "The asymmetric unit of the title compound, [Mn 2 (C 6 H 6 O 7 ) 2 (H 2 O) 4 ]·C 12 H 12 N 2 ·2H 2 O, comprises half of a centrosymmetric dimer, half of a 1,2-bis(pyridin-4-yl)ethane and one water molecule. Two citrate ligands bridge two Mn II ions, the Mn II ion being coordinated by four O atoms from the citrate(2−) ligands and two water O atoms, forming a distorted octahedral environment. In the crystal, O—H...O hydrogen bonds link the centrosymmetric dimers and lattice water molecules into a three-dimensional structure which is further stabilized by intermolecular π–π interactions [centroid–centroid distance = 3.792 (2) Å]." @default.
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- W2037700187 date "2012-07-25" @default.
- W2037700187 modified "2023-10-07" @default.
- W2037700187 title "Bis(μ-2-carboxymethyl-2-hydroxybutanedioato)bis[diaquamanganese(II)]–1,2-bis(pyridin-4-yl)ethane–water (1/1/2)" @default.
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- W2037700187 doi "https://doi.org/10.1107/s1600536812032771" @default.
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