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- W2037707910 abstract "Diffusion and electromigration of hydrogen in PdH0.1, Pd77Ag23H0.1 and Pd50Ag50H0.1 alloy were measured by means of resistivity method. It is known that hydrogen migrates towards the cathode within the temperature range of 300–473 K in the PdH0.1 and Pd77Ag23H0.1 system. In Pd50Ag50H0.1, hydrogen migrates towards the cathode below 400 K, but towards the anode at higher temperatures. Its effective valency increases together with temperature. At the same time it satisfies the linear dependence on inverse specific resistance ρ: Zeff=Zi+(k/ρ). The constants Zi and k have the following values: (1.05±0.01) and −(3.81±0.04)×10−8 Ω m for hydrogen in PdH0.1, (0.73±0.01) and −(11,82±0.03)×10−8 Ω m for hydrogen in Pd77Ag23H0.1, and (0.79±0.04) and −(29.4±1.4)×10−8 Ω m for hydrogen in Pd50Ag50H0.1, respectively. The activation energies of hydrogen diffusion amount to (0.23±0.001) eV/at. for PdH0.1, (0.221±0.006) eV/at. for Pd77Ag23H0.1 and (0.31±0.02) eV/at. for Pd50Ag50H0.1 alloys, respectively." @default.
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- W2037707910 date "1999-01-01" @default.
- W2037707910 modified "2023-09-24" @default.
- W2037707910 title "Investigation of diffusion and electromigration of hydrogen in palladium and PdAg alloy" @default.
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- W2037707910 doi "https://doi.org/10.1016/s0925-8388(98)00694-x" @default.
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