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• W2037744585 startingPage "4494" @default.
• W2037744585 abstract "An efficient protocol for the stereoselective synthesis of 1,3-syn and -anti-tetrahydropyrimidinones (syn- and anti-11a) is reported. The modular procedure is based on a stereodivergent cyclization of readily available urea-type substrates (10a) by intramolecular allylic substitution. The cyclization proceeds with excellent yield (up to 99%) and selectivity (up to dr > 20:1), purely based on substrate control. The product pyrimidines can be readily transformed into the corresponding free syn- and anti-amines." @default.
• W2037744585 created "2016-06-24" @default.
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• W2037744585 date "2010-09-10" @default.
• W2037744585 modified "2023-10-04" @default.
• W2037744585 title "Stereodivergent Synthesis of 1,3-<i>syn</i>- and -<i>anti</i>-Tetrahydropyrimidinones" @default.
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• W2037744585 doi "https://doi.org/10.1021/ol101755m" @default.
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• W2037744585 hasPublicationYear "2010" @default.
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