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• W2037791410 abstract "trans-Fe(depe)2I2 (depe =1,2-bis(diethylphosphino)ethane) was employed to stepwise incorporate Fe(II) centers into a rigid-rod butadiyne based 5,10,15,20-tetraferratetracosa-1,3,6,8,11,13,16,18,21,23-decayne. The iterative synthesis first connects two Fe(II) centers via a central butadiynediyl ligand to provide I-Fe(depe)2-C4-Fe(depe)2-I (2), then extends the system by substituting the terminal halides of 2 to yield Me3SiC4-Fe(depe)2-C4-Fe(depe)2-C4SiMe3 (3). Further modification of the termini gives the deprotected and stannylated compounds RC4-Fe(depe)2-C4-Fe(depe)2-C4R (4 and 5; R = H, Sn(CH3)3, respectively). Transmetalation with two more mononuclear units furnishes the homometallic tetranuclear compound I-Fe(depe)2-C4-Fe(depe)2-C4-Fe(depe)2-C4-Fe(depe)2-I (6), to which two more butadiynyl units were attached to give Me3SiC4-Fe(depe)2-C4-Fe(depe)2-C4-Fe(depe)2-C4-Fe(depe)2-C4SiMe3 (7). All compounds were characterized by NMR, IR, and Raman spectroscopies and by elemental analyses. X-ray diffraction studies were carried out on the dinuclear complexes revealing highly symmetrical rigid-rod structures. Cyclic voltammetric studies showed that compounds 2-7 undergo reversible and well-defined oxidations with high Kc values indicating thermodynamically stable mixed valence species. While the number of the oxidation waves of compounds 2, 6, and 7 are equivalent to the number of metal centers, the dinuclear complexes 3, 4, and 5 exhibit three reversible oxidation waves, one at significantly more positive potential. Two redox waves were attributed to the oxidation of the metal centers, while the remaining one is due to the oxidation of the butadiynediyl ligand. The electronic properties of complexes 2, 3, and 7 were investigated by spectroelectrochemical measurements." @default.
• W2037791410 created "2016-06-24" @default.
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• W2037791410 date "2013-03-05" @default.
• W2037791410 modified "2023-10-18" @default.
• W2037791410 title "Stepwise Construction of an Iron-Substituted Rigid-Rod Molecular Wire: Targeting a Tetraferra–Tetracosa–Decayne" @default.
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• W2037791410 cites W1966377407 @default.
• W2037791410 cites W1968732229 @default.
• W2037791410 cites W1972480447 @default.
• W2037791410 cites W1973779222 @default.
• W2037791410 cites W1977152045 @default.
• W2037791410 cites W1977592516 @default.
• W2037791410 cites W1977967631 @default.
• W2037791410 cites W1979802434 @default.
• W2037791410 cites W1990328746 @default.
• W2037791410 cites W1990608394 @default.
• W2037791410 cites W1994074263 @default.
• W2037791410 cites W1994413104 @default.
• W2037791410 cites W1997710634 @default.
• W2037791410 cites W2005197716 @default.
• W2037791410 cites W2009852209 @default.
• W2037791410 cites W2010411541 @default.
• W2037791410 cites W2011615481 @default.
• W2037791410 cites W2014126110 @default.
• W2037791410 cites W2016661813 @default.
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• W2037791410 cites W2021314628 @default.
• W2037791410 cites W2022063555 @default.
• W2037791410 cites W2028466864 @default.
• W2037791410 cites W2032657118 @default.
• W2037791410 cites W2035317789 @default.
• W2037791410 cites W2037489527 @default.
• W2037791410 cites W2040865037 @default.
• W2037791410 cites W2043887052 @default.
• W2037791410 cites W2044075644 @default.
• W2037791410 cites W2046288608 @default.
• W2037791410 cites W2049136499 @default.
• W2037791410 cites W2049381652 @default.
• W2037791410 cites W2052409934 @default.
• W2037791410 cites W2052536920 @default.
• W2037791410 cites W2053708450 @default.
• W2037791410 cites W2055550841 @default.
• W2037791410 cites W2056381273 @default.
• W2037791410 cites W2058383881 @default.
• W2037791410 cites W2063151161 @default.
• W2037791410 cites W2066985810 @default.
• W2037791410 cites W2074573245 @default.
• W2037791410 cites W2076029145 @default.
• W2037791410 cites W2081062251 @default.
• W2037791410 cites W2082529064 @default.
• W2037791410 cites W2083721980 @default.
• W2037791410 cites W2085302815 @default.
• W2037791410 cites W2088481620 @default.
• W2037791410 cites W2089250442 @default.
• W2037791410 cites W2092460261 @default.
• W2037791410 cites W2095351425 @default.
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• W2037791410 cites W2117940643 @default.
• W2037791410 cites W2138289499 @default.
• W2037791410 cites W2147294959 @default.
• W2037791410 cites W2147736649 @default.
• W2037791410 cites W2148469323 @default.
• W2037791410 cites W2158487394 @default.
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• W2037791410 cites W2318188976 @default.
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• W2037791410 doi "https://doi.org/10.1021/ja400078c" @default.
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